Webster, Alyssa A’s team published research in Dalton Transactions in 2019 | 1762-41-0

Dalton Transactions published new progress about Hydrides Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), PROC (Process), RACT (Reactant or Reagent), PREP (Preparation) (bipyridine rhenium hydrides). 1762-41-0 belongs to class pyridine-derivatives, and the molecular formula is C10H6Cl2N2, COA of Formula: C10H6Cl2N2.

Webster, Alyssa A.; Huo, Jianqiang; Milliken, Jenna; Sullivan, Pat; Kubelka, Jan; Hoberg, John O. published the artcile< Hydrogen gas formation from the photolysis of rhenium hydrides - mechanistic and computational studies>, COA of Formula: C10H6Cl2N2, the main research area is dihydrogen elimination kinetics photolysis bipyridine rhenium hydride substituent effect; bipyridine rhenium hydride preparation kinetics photolysis dihydrogen elimination; optimized geometry bipyridine rhenium hydride photolysis dihydrogen elimination DFT.

The photolysis of 4,4′-disubstituted, 2,2′-bipyridine fac-Re(bpy)(CO)3H derivatives produces stoichiometric H2 gas. The rate of production varies greatly depending on the electronic nature of the disubstituted bipyridine (bpy) with halogenated substituents increasing the rate. Isotope labeling studies along with B3LYP geometry optimization DFT modeling studies indicate a mechanism involving a Re-H-Re bridging complex that leads to a dimeric Re-Re(η2-H2) state prior to dissociating H2 gas.

Dalton Transactions published new progress about Hydrides Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), PROC (Process), RACT (Reactant or Reagent), PREP (Preparation) (bipyridine rhenium hydrides). 1762-41-0 belongs to class pyridine-derivatives, and the molecular formula is C10H6Cl2N2, COA of Formula: C10H6Cl2N2.

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem