Category: pyridine-derivatives. Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; N-HETEROCYCLIC CARBENE; PYRAZOLYL-IMIDAZOLYL LIGAND; CATALYTIC-ACTIVITY; BEARING; KETONES; EFFICIENT; CONSTRUCTION; NITRILES; IMPACT, Saw an article supported by the Council of Scientific and Industrial Research (CSIR) New Delhi, IndiaCouncil of Scientific & Industrial Research (CSIR) – India [01(2942)/18/EMR-II]. Published in WILEY in HOBOKEN ,Authors: Singh, PR; Maji, A; Singh, O; Singh, UP; Ghosh, K. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone
Ruthenium complexes(1-3) have been synthesized using pincer-type ligands L-1 = (E)-2-((2-phenyl-2-(pyridin-2-yl)hydrazono)methyl)pyridine, L-2 = (E)-2-(1-phenyl-2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)pyridine, L-3 = (E)-2-(phenyl(2-phenyl-2-(pyridin-2-yl)hydrazono) methyl)pyridine. The molecular structures of all the complexes 1, 2 and 3 were determined by using single crystal X-ray diffraction. These complexes showed excellent catalytic activities such as transfer hydrogenation and alcohol oxidation. Theoretical calculations have been performed to understand the electronic properties of all the complexes using B3LYP as a function and LANL2DZ as a basis set.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem