An article Manganese-catalysed divergent silylation of alkenes WOS:000598710300003 published article about SELECTIVE DEHYDROGENATIVE SILYLATION; HYDROSILYLATION REACTIONS; ATOM-TRANSFER; REACTIVITY; CONVERSION; COMPLEXES; MECHANISM; OLEFINS; BONDS; SCOPE in [Dong, Jie; Yan, Zhongfei; Ma, Junyang; Zhu, Chengjian; Xie, Jin] Nanjing Univ, Jiangsu Key Lab Adv Organ Mat Chem & Biomed, State Key Lab Coordinat Chem, Innovat Ctr ChemBIC,Sch Chem & Chem Engn, Nanjing, Peoples R China; [Yuan, Xiang-Ai; Mu, Liying] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu, Shandong, Peoples R China; [Yan, Zhongfei] Anyang Normal Univ, Coll Chem & Chem Engn, Anyang, Peoples R China; [Zhu, Chengjian] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou, Peoples R China in 2021, Cited 55. SDS of cas: 614-18-6. The Name is Ethyl nicotinate. Through research, I have a further understanding and discovery of 614-18-6
Transition-metal-catalysed, redox-neutral dehydrosilylation of alkenes is a long-standing challenge in organic synthesis, with current methods suffering from low selectivity and narrow scope. In this study, we report a general and simple method for the manganese-catalysed dehydrosilylation and hydrosilylation of alkenes, with Mn-2(CO)(10) as a catalyst precursor, by using a ligand-tuned metalloradical reactivity strategy. This enables versatility and controllable selectivity with a 1:1 ratio of alkenes and silanes, and the synthetic robustness and practicality of this method are demonstrated using complex alkenes and light olefins. The selectivity of the reaction has been studied using density functional theory calculations, showing the use of an (PrPNP)-Pr-i ligand to favour dehydrosilylation, while a JackiePhos ligand favours hydrosilylation. The reaction is redox-neutral and atom-economical, exhibits a broad substrate scope and excellent functional group tolerance, and is suitable for various synthetic applications on a gram scale.
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Reference:
Pyridine – Wikipedia,
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