Yang, J; Deng, YF; Zhang, YZ in [Yang, Jiong; Deng, Yi-Fei; Zhang, Yuan-Zhu] Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China published Two azido-bridged homospin Fe(ii)/Co(ii) coordination polymers featuring single-chain magnet behavior in 2020.0, Cited 72.0. Recommanded Product: 91-02-1. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.
Two azido-bridged homospin Fe(ii)/Co(ii) coordination polymers [Fe-2(Bzp)(2)(N-3)(4)](n) (1) and [Co-4(Bzp)(4)(N-3)(8)(MeOH)(2)](n) (2) (bzp = 2-benzoylpyridine) are prepared, which consist of one-dimensional neutral chains with pure EO-azido (mu(2)-1,1-N-3) bridges. Magnetically, both 1 and 2 exhibit considerable intrachain ferromagnetic interactions which benefit from the EO-azido bridging mode, leading to typical single-chain magnet (SCM) behavior under both the infinite-size and finite-size regime and pronounced hysteresis loops. As far as the bridging network is concerned, complex 1 represents not only a rare example of homospin Fe(ii)-based SCMs but also the first Fe(ii) chain compound with pure EO-azido bridges.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem