Recently I am researching about C-H AMINATION; HETEROCYCLIC CARBENE COMPLEXES; BOND FUNCTIONALIZATION; EFFICIENT SYNTHESIS; NATURAL-PRODUCTS; ALKYNES; N-SULFONYL-1,2,3-TRIAZOLES; THERMOCHEMISTRY; CYCLOADDITION; CONSTRUCTION, Saw an article supported by the DST, Government of IndiaDepartment of Science & Technology (India) [EMR/2016/000010]; CSIR-CSMCRICouncil of Scientific & Industrial Research (CSIR) – India [MLP-027, OLP-088]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Rawat, D; Ravi, C; Joshi, A; Suresh, E; Jana, K; Ganguly, B; Adimurthy, S. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone. Quality Control of Phenyl(pyridin-2-yl)methanone
Pyrido[1,2-a]indoles are known for medicinally and pharmaceutically important compounds; however, the efficient synthetic routes are scarce in the literature. We report herein a convenient and efficient route to synthesize these molecules through indium-catalyzed transannulation of pyridotriazoles with arenes. A library of compounds have been synthesized employing the method developed with various substituted pyrido[1,2-a]indole derivatives in moderate to good yields. The density functional theory study using SMDDCB-M06/6-31++G(d,p)/LANL2DZ//B3LYP/6-31G(d)/LANL2DZ method suggests that the reactions proceed via indium-carbenoid complex.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem