Xiao, Yue; Li, Yang; Zhang, Bohan; Li, Hui; Cheng, Zehong; Shi, Jianqiao; Xiong, Jing; Bai, Yugang; Zhang, Ke published the artcile< Functionalizable, Side Chain-Immolative Poly(benzyl ether)s>, Related Products of 2127-03-9, the main research area is selfimmolative polybenzylether.
Herein, we report a poly(benzyl ether)-based self-immolative polymer (SIP) with pendant pyridine disulfide groups. Cleavage of the side-chain disulfides leads to the formation of phenolates, which initiate depolymerization from the side chain. Due to the higher d. of the disulfide groups compared to that of the chain-end-capping group, which normally is responsible for initiating depolymerization of SIPs, the side chain-immolative polymer (ScIP) can be readily degraded in the solid state where the mobility of polymer chains is substantially limited. The ScIP was also further modified through the thiol-disulfide exchange reaction to prepare ScIP-g-poly(ethylene glycol) graft polymers and organogels, which were also able to undergo complete reductive self-immolative degradation
ACS Macro Letters published new progress about Depolymerization. 2127-03-9 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2S2, Related Products of 2127-03-9.