Yang, Chu-Ting published the artcilePd-Catalyzed Vinylation of Aryl Halides with Inexpensive Organosilicon Reagents Under Mild Conditions, Application In Synthesis of 21190-89-6, the main research area is aryl chloride bromide organosilicon reagent vinylation palladium catalyst; Am/Cm separation; cross-coupling; palladium; silicon; substituent effects.
Pd-catalyzed Hiyama vinylation reaction of non-activated aryl chlorides and bromides under mild conditions was developed. The use of efficient vinyl donors and electron-rich sterically hindered phosphine ligands was critical for the success of the reaction. The products of this transformation can be used for Am/Cm separation, an important challenge in nuclear fuel reprocessing. The substituent effect on Am/Cm separating selectivity was also achieved, which could contribute to the development of new chromatog. materials for the separation of Am and Cm.
Chemistry – A European Journal published new progress about Aryl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 21190-89-6 belongs to class pyridine-derivatives, name is Ethyl 6-chloropicolinate, and the molecular formula is C8H8ClNO2, Application In Synthesis of 21190-89-6.