Reference of 2,5-DibromopyridineIn 2021 ,《Ultrahigh thermal-stability polyimides with low CTE and required flexibility by formation of hydrogen bonds between poly(amic acid)s》 appeared in European Polymer Journal. The author of the article were Yang, Zhenghui; Ma, Pingchuan; Li, Furong; Guo, Haiquan; Kang, Chuanqing; Gao, Lianxun. The article conveys some information:
The flexibility of organic light-emitting diode (OLED) displays highly depends on the properties of the flexible substrates. In this paper, a series of aromatic polyimides have been fabricated via the copolycondensation of pyromellitic dianhydride (PMDA), the two different rigid heterocyclic diamines, 2,5-bis(4-aminophenyl)pyrimidine (PRM) or 2,5-bis(4-aminophenyl)pyridine (PRD), and another flexible diamine, 4,4′-oxydianiline (ODA). The performance of the polyimide films could be systematically tailored by means of adjusting the main-chain rigidity, as well as the close packing and orientation of polymer chains by the formation of the intermol. hydrogen bonds between poly(amic acid)s. The optimal results (PIb-4, PIb-5, PIc-2) showed that the polyimides were endowed with ultra-high glass transition temperature (Tg) exceeding 450°C, low coefficient of thermal expansion (CTE) at 0-5 ppm K-1 and excellent thermal stability (Td5% = 570-590°C). Meanwhile, all of them exhibited sufficient flexibility, the elongation at break at of 40-60%, extremely high tensile strength of 250-380 MPa and modulus of 4.1-6.1 GPa. Hence, the polyimide films should be the promising candidates for application as the polymer substrates for flexible OLED displays. In the part of experimental materials, we found many familiar compounds, such as 2,5-Dibromopyridine(cas: 624-28-2Reference of 2,5-Dibromopyridine)
2,5-Dibromopyridine(cas: 624-28-2) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Reference of 2,5-Dibromopyridine