Ru-Catalyzed ortho-Selective Diborylation of 2-Arylpyridines toward the Construction of 锜?Conjugated Functions was written by Yao, Wubing;Wang, Jiali;He, Lili;Cao, Dongdong;Yang, Jianguo. And the article was included in Journal of Organic Chemistry in 2020.Electric Literature of C11H9NO This article mentions the following:
A Ru catalytic ortho-C-H diborylation of 2-arylpyridine derivatives, including challenging 2-phenoxypyridine functions, using a remarkably low catalyst loading and a low-cost and bench-stable B source, was developed. The novel strategy shows high activity with excellent selectivity and may offer a versatile and green alternative to currently employed high loadings of noble metals or extra additives for the selective borylations. In the experiment, the researchers used many compounds, for example, 2-Phenoxypyridine (cas: 4783-68-0Electric Literature of C11H9NO).
2-Phenoxypyridine (cas: 4783-68-0) belongs to pyridine derivatives. Pyridine’s the lone pair does not contribute to the aromatic system but importantly influences the chemical properties of pyridine, as it easily supports bond formation via an electrophilic attack. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Electric Literature of C11H9NO