Yoshida, Hiroto published the artcileDirect Suzuki-Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons, Safety of 5-Methyl-2-(p-tolyl)pyridine, the publication is ACS Catalysis (2020), 10(1), 346-351, database is CAplus.
The direct Suzuki-Miyaura coupling with “protected” R-B(dan) (dan = naphthalene-1,8-diaminato) (R = Ph, 4-MeOC6H4, 2-pyridyl) was demonstrated to smoothly occur without in situ deprotection of the B(dan) moiety. The use of KOt-Bu (Ba(OH)2 in some cases) as a base under anhydrous conditions is the key to the successful cross-coupling, where R-B(dan) is readily converted into a transmetalation-active borate-form, regardless of the well-accepted diminished boron-Lewis acidity.
ACS Catalysis published new progress about 85237-71-4. 85237-71-4 belongs to pyridine-derivatives, auxiliary class Pyridine,Benzene, name is 5-Methyl-2-(p-tolyl)pyridine, and the molecular formula is C10H12BF3KNO2, Safety of 5-Methyl-2-(p-tolyl)pyridine.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem