I found the field of Chemistry; Science & Technology – Other Topics; Engineering very interesting. Saw the article Ultralow Loading Cobalt-Based Nanocatalyst for Benign and Efficient Aerobic Oxidation of Allylic Alcohols and Biobased Olefins published in 2019.0. Recommanded Product: 500-22-1, Reprint Addresses Tao, DJ (corresponding author), Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China.; Li, CZ (corresponding author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China.. The CAS is 500-22-1. Through research, I have a further understanding and discovery of 3-Pyridinecarboxaldehyde
The synthesis of alpha,beta-unsaturated ketones from aerobic oxidation of allylic alcohols and biobased olefins serves as an important topic in green and sustainable chemistry. In this work, we report the utilization of a sacrificial template ZIF-8 for preparation of mesoporous Co-0.05/N-C material with an ultralow cobalt loading of 0.05 wt %, in which the excellent catalytic performance in aerobic oxidation of alpha-pinene and cinnamyl alcohol was achieved with an 85% yield of verbenone and a yield of cinnamaldehyde, respectively. The results of control experiments and several characterization investigations further illustrate that the sacrificial template ZIF-8 plays a key role to disperse well metallic cobalt in the Co-0.05/N-C-800 catalyst and an appropriate cobalt content of 0.05 wt % is beneficial for benign and efficient aerobic oxidation of various allylic alcohols and biobased olefins. In addition, the Co0.05/N-C-800 catalyst also exhibited good stability and reusability for recovering and reusing at least six times without obvious decrease in catalytic activity. The presented efficient nanocatalyst thus triggers facile synthesis of a series of alpha,beta-unsaturated aldehydes/ketones in high yields.
About 3-Pyridinecarboxaldehyde, If you have any questions, you can contact Zhao, X; Zhou, Y; Huang, K; Li, CZ; Tao, DJ or concate me.. Recommanded Product: 500-22-1
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem