Zhang, Youcan; Yin, Zhiping; Wang, Hai; Wu, Xiao-Feng published the artcile< Pd/C-Catalyzed Carbonylative Synthesis of 2-Aminobenzoxazinones from 2-Iodoaryl Azides and Amines>, COA of Formula: C6H8N2, the main research area is amine iodoaryl azide carbon monoxide palladium catalyst carbonylation; aminobenzoxazinone preparation.
A palladium-catalyzed carbonylative procedure for the synthesis of 2-aminobenzoxazinones from 1-azido-2-iodobenzenes and amines has been developed. A broad range of 2-aminobenzoxazinone derivatives, e.g., I were prepared in moderate to excellent yields by using Pd/C as the catalyst under CO atm. Notably, by using organic azides as the substrates, external oxidant usage can be successfully avoided and only forms N2 as the byproduct.
Organic Letters published new progress about Amines Role: RCT (Reactant), RACT (Reactant or Reagent). 3731-53-1 belongs to class pyridine-derivatives, and the molecular formula is C6H8N2, COA of Formula: C6H8N2.